Abstract
Platinum-based catalysts have a long history of application in formic acid oxidation (FAO). The single metal Pt is active in FAO but expensive, scarce, and rapidly deactivates. Understanding the mechanism of FAO over Pt important for the rational design of catalysts. Pt nanomaterials rapidly deactivate because of the CO poisoning of Pt active sites via the dehydration pathway. Alloying with another transition metal improves the performance of Pt-based catalysts through bifunctional, ensemble, and steric effects. Supporting Pt catalysts on a high-surface-area support material is another technique to improve their overall catalytic activity. This review summarizes recent findings on the mechanism of FAO over Pt and Pt-based alloy catalysts. It also summarizes and analyzes binary and ternary Pt-based catalysts to understand their catalytic activity and structure relationship.