Abstract
Potassium-ion batteries (PIBs) are appealing alternatives to conventional lithium-ion batteries (LIBs) because of their wide potential window, fast ionic conductivity in the electrolyte, and reduced cost. However, PIBs suffer from sluggish K+ reaction kinetics in electrode materials, large volume expansion of electroactive materials, and the unstable solid electrolyte interphase. Various strategies, especially in terms of electrode design, have been proposed to address these issues. In this review, the recent progress on advanced anode materials of PIBs is systematically discussed, ranging from the design principles, and nanoscale fabrication and engineering to the structure-performance relationship. Finally, the remaining limitations, potential solutions, and possible research directions for the development of PIBs towards practical applications are presented. This review will provide new insights into the lab development and real-world applications of PIBs.