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Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy
Journal article   Peer reviewed

Redox mediation enabled by immobilised centres in the pores of a metal-organic framework grown by liquid phase epitaxy

Andre Dragaesser, Osama Shekhah, Olexandra Zybaylo, Cai Shen, Manfred Buck, Christof Woell and Derck Schlettwein
Chemical communications (Cambridge, England), Vol.48(5), pp.663-665
18/01/2012
DOI: https://doi.org/10.1039/c1cc16580a
PMID: 22138894

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
A layer of a metal-organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

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