Abstract
The present study describes synthesis and characterization of diacrylamidoxime triaethylenetetralevopimaramide (DPAO) and its use in surface modification of Fe3O4 magnetic nanoparticles to obtain DPAO-based magnetic nanoparticles (DPAO-MNPs). The prepared composite was characterized by FTIR, 1HNMR, XRD, DLS, TEM, SEM and EDX. Vibrating sample magnetometer is used to determine the magnetic properties of DPAO-MNPs. Results of analyses indicate that the surface of Fe3O4 was successfully capped with DPAO. The adsorption features of the prepared composite towards thorium ions were investigated in a batch system. Kinetic study of Th(IV) adsorption on DPAO-MNPs indicate the adsorption equilibrium achieved within 150 min and is pH dependent. The adsorption results were described mathematically using Langmuir and Freundlich sorption models. The composite showed a maximum Th(IV) loading capacity of 666 mg/g at 25 °C and pH 4. The thermodynamic results indicated that the adsorption process was thermodynamically favorable, spontaneous and endothermic nature. The obtained results suggest that DPAO-MNPs composite may be considered as a potential fast, effective and simple adsorbent for sorption thorium(IV) from water.
•New low cost magnetic nanoparticles composite (DPAO-MNPs) prepared with high yield.•DPAO-MNPs showed fast, effective adsorption for removal of thorium (IV) from water.•DPAO-MNPs showed high removal efficiency of water pollutants.