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Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation
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Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation

Damir A. Safin, Yang Xu, Ilia Korobkov, David L. Bryce and Muralee Murugesu
CrystEngComm, Vol.15(48), pp.10419-10422
01/01/2013
DOI: https://doi.org/10.1039/c3ce42146e

Abstract

Chemistry Chemistry, Multidisciplinary Crystallography Physical Sciences Science & Technology
An unprecedented dinuclear heteroleptic Cd-II complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand, which can be seen as a triply fused terpyridine ligand. In the obtained complex, TPymT retains its structural integrity without undergoing oft-observed hydrolysis.

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