Abstract
This perspective proposes a potential pathway to diminish atmospheric CO2 accumulations which is distinct from traditional carbon capture and geological sequestration strategies and from existing negative emissions technologies (NETs). Unlike conventional sorbent- or solvent-based CO2 capture processes where substantial energy expenditures are associated with demixing and desorbing CO2, the single-step carbon sequestration and storage (sCS(2)) approach relies on electrolytic carbonate mineral precipitation using renewable energy within a simple and scalable process design. Although numerous approaches have implied electrolysis for carbon management, the sCS(2) approach is unique in the following ways: (1) CO2 mineralization for promoting solid carbonate formation: The thermodynamic and kinetic barriers to carbonate precipitation are overcome by direct and in situ electrochemical forcing to stabilize dissolved inorganic carbon and divalent cations [Ca,Mg] to form carbonate minerals. (2) Flow-through membraneless electrolysis: A flowing electrolyte (seawater) is dissociated while in motion. The process utilizes cost-effective mesh electrodes while also decreasing the number of components and assembly steps and reducing the risk of device failure. (3) Integrated electrolytic reactor-rotary drum filter: An electroactive thinfilm mesh cathode (eTFC) is suggested to be integrated within a rotary drum filter configuration, allowing for the filtration of dilute and polydispersed mineral precipitates at a low energy cost. These attributes render sCS(2) as an approach worthy of more detailed evaluation, development, and scaling for global-scale carbon management.