Selective formation of propene from CO + H2 or C2H4 with Fe3(CO)12 supported on inorganic oxides. mechanistic implication in Fischer-Tropsch synthesis

Françlois Hugues; Bernard Besson; Jean M Basset

doi:10.1039/C39800000719

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Journal article

Selective formation of propene from CO + H2 or C2H4 with Fe3(CO)12 supported on inorganic oxides. mechanistic implication in Fischer-Tropsch synthesis

Françlois Hugues, Bernard Besson and Jean M Basset

Journal of the Chemical Society, Chemical Communications, (15), pp.719-721

1980

DOI: https://doi.org/10.1039/C39800000719

Abstract

When a catalyst derived from Fe 3 (CO) 12 supported on magnesia is treated either with CO + H 2 or C 2 H 4 propene is formed selectively; this can be explained on the basis of a carbene + olefin metallacyclobutane mechanism.

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Title: Selective formation of propene from CO + H2 or C2H4 with Fe3(CO)12 supported on inorganic oxides. mechanistic implication in Fischer-Tropsch synthesis
Creators - without role: Françlois Hugues
Bernard Besson
Jean M Basset
Publication Details: Journal of the Chemical Society, Chemical Communications, (15), pp.719-721
Number of pages: 3
Identifiers: 9944254808331
Academic Unit: King Abdullah University of Science & Technology
Resource Type: Journal article