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Self-Assembly of a Stable Silver Thiolate Nanocluster Encapsulating a Lacunary Keggin Phosphotungstate Anion
Journal article   Peer reviewed

Self-Assembly of a Stable Silver Thiolate Nanocluster Encapsulating a Lacunary Keggin Phosphotungstate Anion

Bing-Jie Yan, Xiang-Sha Du, Ren-Wu Huang, Jin-Sen Yang, Zhao-Yang Wang, Shuang-Quan Zang and Thomas C. W. Mak
Inorganic chemistry, Vol.57(9), pp.4828-4832
07/05/2018
DOI: https://doi.org/10.1021/acs.inorgchem.8b00702
PMID: 29697246

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
A polyoxometalate-templated silver(I) thiolate nanocluster has been synthesized by a one-pot reaction in high yield. This novel and stable nanocluster exhibits a core-shell structure with a Ag67S36 shell and two lacunary Keggin [PW9O34](9-) cores, which is fully characterized by X-ray crystallography, X-ray photoelectron spectroscopy, UV-vis, powder X-ray diffraction, and cyclic voltammetry.

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