Abstract
•Novel Cadion bonded polyurethane foam as selective sorbent.•Binary elements (Cd &Ni) on-line SPE spectrophotometric determination.•Comparable or better detection limit to other UV–Vis detection methods.•Successful application to real samples with good recovery and precision.
A simultaneous spectrophotometric method was developed for the rapid determination of the binary elements nickel and cadmium. Two polyurethane foam sorbents, cadion functionalized foam and untreated foam, were separately packed in two minicolumns and used for on-line preconcentration/separation. The two elements were separated/preconcentrated on the cadion- foam minicolumn, and then they were eluted by hydrochloric acid and mixed with a thiocyante stream before entering the untreated foam minicolumn. Nickel passed out to react with 4-(2-pyridylazo)-resorcinol reagent and measured spectrophotometrically at 498 nm. The adsorbed cadmium-thiocyanate on the untreated foam was further eluted by sodium hydroxide and identically detected. At a preconcentration time of 60 sec (100 µg L−1), the detection limit was 4.6 and 3.3 µg L−1 and the quantification limit was 15.3 and 11.0 µg L−1 for cadmium and nickel, respectively. The preconcentration factor was 5.0 and 11.0, respectively, and sampling frequency was 12 and 20 h−1. The accuracy was assessed using the BCR397R human hair and NIST 1577b bovine liver certified reference materials with a recovery of 92.0–94.2% (Relative standard deviation = 5.3–8.2%). The analysis of human urine and tap water samples demonstrated the applicability of the method and showed a relative recovery of 89.6 to106% (Relative standard deviation ≤ 9.4%).