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[( SiO)Ta-V(=CH2)Cl-2], the first tantalum methylidene species prepared and identified on the silica surface
Journal article   Peer reviewed

[( SiO)Ta-V(=CH2)Cl-2], the first tantalum methylidene species prepared and identified on the silica surface

Yin Chen, Emmanuel Callens, Edy Abou-hamad and Jean-Marie Basset
Journal of organometallic chemistry, Vol.744, pp.3-6
01/11/2013
DOI: https://doi.org/10.1016/j.jorganchem.2013.04.050

Abstract

Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology
A novel surface tantalum methylidene [( SiO)Ta-V(=CH2)Cl-2] was obtained via thermal decomposition of the well-defined surface species [( SiO)(TaCl2Me2)-Cl-V]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the alpha-hydrogen abstraction reaction has also been investigated in the heterogeneous system. (C) 2013 Elsevier B.V. All rights reserved.

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