Abstract
Silane/ceramic combination provides the composites with several advantages from the advancements of new ceramic composite materials with good thermal conductivity, high mechanical and dielectric properties have wide significant applications in electrical and electronic industries. In this study, to enhance the dispersibility of dielectric barium titanate (BaTiO3) ceramic powder and additives for the fabrication of multilayer ceramic capacitors (MLCCs), surface treatment of the precursor of ceramic powder was performed using silane coupling agents. Dielectric ceramic sheets fabricated from ceramic powders that had been surface-treated with different amounts of N-[3-(trimethoxysilyl)propyl]aniline (TMSPA) which increased the surface gloss. In particular, the dielectric properties of the multilayer ceramic sheet fabricated by stacking sheets from the TMSPA-treated ceramic powder sintering at 1200 °C, it was confirmed that the dielectric constant increased from 881 to 2382 and the dielectric loss dropped from 1.96 to 1.34% with utilization of the TMSPA treatment. The physical and dielectric properties of the TMSPA-treated multilayer ceramic sheet were also determined by Fourier-transform infrared spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, glossmetry, and electrochemical impedance analysis. The results revealed that the TMSPA-modified BaTiO3 surfaces considerably increased the dielectric property of the fabricated nanocomposite.
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•Effect of silane coupling agent TMSPA on BaTiO3 ceramic sheets investigated.•TMSPA treatment enhances dielectric properties of multilayer ceramic sheets.•Sintering temperature also affects dielectric properties and densification.•Optimal conditions are 0.5 wt% TMSPA and sintering at 1200 °C.