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Silicon-Naphthalo/Phthalocyanine-Hybrid Sensitizer for Efficient Red Response in Dye-Sensitized Solar Cells
Journal article   Peer reviewed

Silicon-Naphthalo/Phthalocyanine-Hybrid Sensitizer for Efficient Red Response in Dye-Sensitized Solar Cells

Bogyu Lim, George Y. Margulis, Jun-Ho Yum, Eva L. Unger, Brian E. Hardin, Michael Graetzel, Michael D. McGehee, Alan Sellinger and Mohammad K Nazeeruddin
Organic letters, Vol.15(4), pp.784-787
15/02/2013
PMID: 23384416

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
Introduction of a naphthalocyanine moiety to phthalocyanine allows for a gradual red shift of the absorption spectrum in the resulting chromophore. Using silicon as a core atom allows for the Introduction of additional siloxane side chains which mitigate dye aggregation. A dye-sensitized solar cell with this hybrid sensitizer exhibits a broad and flat IPCE of 80% between 600 and 750 nm and high photocurrent densities of 19.0 mA/cm(2).

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