Single-crystal EPR and theoretical investigations on the 'paramagnetic impurity' (n-B4N)(2)[Cu(mnt)(2)] built upon preparation of the antiferromagnetically coupled binuclear (n-Bu4N)(2)[(mnt)Cu(tto)Cu(mnt)]

G Teschmit; P Strauch; A Barthel; J Reinhold; R Kirmse

doi:10.1016/S0020-1693(99)00400-4

Back

Single-crystal EPR and theoretical investigations on the 'paramagnetic impurity' (n-B4N)(2)[Cu(mnt)(2)] built upon preparation of the antiferromagnetically coupled binuclear (n-Bu4N)(2)[(mnt)Cu(tto)Cu(mnt)]

Journal article

Peer reviewed

Single-crystal EPR and theoretical investigations on the 'paramagnetic impurity' (n-B4N)(2)[Cu(mnt)(2)] built upon preparation of the antiferromagnetically coupled binuclear (n-Bu4N)(2)[(mnt)Cu(tto)Cu(mnt)]

G Teschmit, P Strauch, A Barthel, J Reinhold and R Kirmse

INORGANICA CHIMICA ACTA, Vol.298(1), pp.94-96

30/01/2000

DOI: https://doi.org/10.1016/S0020-1693(99)00400-4

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

The paramagnetic Cu-II impurity observed by EPR in all prepared samples of the binuclear antiferromagnetically coupled (n-Bu4N)(2)[(mnt)Cu(tto)Cu(mnt)] (mnt = 1,2-dicyanoethene-1,2dithiolate; tto = tetrathiooxalate) has been identified to be [Cu(mnt)(2)](2 -). The experimental data as well as the results from density functional theory (DFT) calculations are used to characterize the spin-density distribution in the mononuclear Cu-II complex. (C) 2000 Elsevier Science S.A. All rights reserved.

Metrics

1 Record Views

Details

Title: Single-crystal EPR and theoretical investigations on the 'paramagnetic impurity' (n-B4N)(2)[Cu(mnt)(2)] built upon preparation of the antiferromagnetically coupled binuclear (n-Bu4N)(2)[(mnt)Cu(tto)Cu(mnt)]
Creators - without role: G Teschmit - Leipzig University
P Strauch - Leipzig University
A Barthel - Leipzig University
J Reinhold - Leipzig University
R Kirmse - Leipzig University
Publication Details: INORGANICA CHIMICA ACTA, Vol.298(1), pp.94-96
Publisher: Elsevier
Number of pages: 3
Identifiers: 9944058808331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article