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Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates
Journal article   Peer reviewed

Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates

A. Ben Khelifa, M. Salah Belkhiria, G. Huang, S. Freslon, O. Guillou and K. Bernot
Dalton transactions : an international journal of inorganic chemistry, Vol.44(37), pp.16458-16464
07/10/2015
DOI: https://doi.org/10.1039/c5dt02377g
PMID: 26314612

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)(8)][ Ce(eta(2)-NO3)(2)(dmso)(4)(alpha-Mo8O26)(0.5)][Mo6O19]. The original electrostatic environment created around the Ce-III by its coordination to the isopolyoxomolybdate core induces complex single-molecule magnet behavior.

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