Abstract
This study was designed to investigate the successive effects of the early Pleistocene subhumid and early to middle Holocene semi-arid paleoclimates and late Holocene to present day arid/hyperarid conditions on pedogenesis and evolution in Harrat Ithnayn volcano in the Arabian Shield, Saudi Arabia. The investigations were conducted using pedological macro and micro-features, physicochemical characteristics, elemental geochemistry, weathering indices and mineralogical analyses for light and heavy sand and clay fractions. The targeted soils developed in a subhumid paleoclimate and are classified as vitric Andisols, which are little to moderately weathered. Subhumid climate effects were evident through the presence of pedogenic Fe (crystalline oxides, Fed = 25 to 58 g kg1), fairly high Feo/Fed (0.24 to 0.87), and the predominance of hydroxy-Al smectite and kaolinite. Residual primary minerals and modern arid conditions simultaneously led to accumulation of secondary salts and carbonates. Exchangeable Ca and Mg pools contributed 21-56 % of total Ca and Mg contents, while exchangeable K contributed only up to 4 %. Soil processes thus involved andisolization, salinization, and calcification. These processes were due to successive moist paleoclimates and the current arid conditions, thus revealing their formation under multiple climates.