Abstract
In this article, the effect of the preparation methods of titanium pyrophosphate (TiPO) catalysts on their catalytic performances via the oxydehydrogenation (ODH) of n-butane has been investigated. The TiPO-A, TiPO-B, and TiPO-S catalysts have been prepared, respectively, by three synthesis methods: (1) liquid–solid, (2) coprecipitation, and (3) solid-state methods. The samples have been characterized by N2-sorption, X-ray diffraction, inductively coupled plasma through the atomic emission spectroscopy, Fourier transform infrared, thermogravimetric analysis, differential scanning calorimetry, field emission scanning electron microscopy, and temperature-programmed desorption (NH3 or CO2). Fourier transform infrared and X-ray diffraction data indicate the presence of a pure TiP2O7 phase in TiPO-A and TiPO-S samples, whereas TiPO-B revealed the presence of an amorphous TiP2O7 and rutile TiO2 phase. The coupled TGA/DSC curves showed that all catalysts are stable up to 600 °C. The catalytic testing, performed at 500 °C in ODH of n-butane, shows that the best yield (11.6%) is obtained over the TiPO-A catalyst, with 22.7% of butane conversion and 51.2% of total butene selectivity (whose 94.6% is the trans-2-butene), and seems to be an important result in this work. Only the TiPO-B1 catalyst produced butadiene with 1.7% (14.2% of ODH product) selectivity; this result is no less crucial.
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•TiP2O7 synthesized in nanoscale to ODH of n-butane.•The catalyst is prepared by solid-phase, solid–liquid, and coprecipitation methods.•The catalyst activity is shown by high density of acid–base sites.•The best yield 11.6% is obtained with 22.7% conversion and 51.2% butenes selectivity.•Coprecipitation catalyst produced butadiene with 14.2% selectivity of all butenes product.