Abstract
Studies have been extended to the ethylene glycol-water solvent system not only in support of the validity and general applicability of the new method developed for the determination of absolute electrode potentials and thermodynamics of single ions, but also to study the solvent effects on single electrode potential and related thermodynamic quantities, in such media. All results showed that the plots of standard transfer free energy or entropy against the reciprocal of the anionic or cationic radius, used earlier to obtain the thermodynamic properties of single ions, cannot be accepted.