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Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front
Journal article   Open access  Peer reviewed

Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front

Danish Iqbal, Adnan Sarfraz, Martin Stratmann and Andreas Erbe
Chemical communications (Cambridge, England), Vol.51(89), pp.16041-16044
01/01/2015
PMID: 26344142

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
After passage of a delamination front at a polymer/zinc interface, pH oscillations and oscillations in the quantity of corrosion products are observed. The reason for these oscillations is the low quantity of water in the confined reaction volume, water consumption by oxygen reduction, and water regeneration after precipitation of ZnO.
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https://doi.org/10.1039/c5cc06468fView
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