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Spray processable green to highly transmissive electrochromics via chemically polymerizable donor-acceptor heterocyclic pentamers
Journal article   Peer reviewed

Spray processable green to highly transmissive electrochromics via chemically polymerizable donor-acceptor heterocyclic pentamers

Pierre M. Beaujuge, Stefan Ellinger and John R. Reynolds
Advanced materials (Weinheim), Vol.20(14), pp.2772-2776
17/07/2008
PMID: 25213905

Abstract

Chemistry Chemistry, Multidisciplinary Chemistry, Physical Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Physical Sciences Physics Physics, Applied Physics, Condensed Matter Science & Technology Science & Technology - Other Topics Technology
Electrochromic polymers (ECPs) of tunable green: Two symmetrical donoracceptor based oligomers were designed, synthesized and chemically polymerized affording solutionprocessable conjugated polymers of distinct green hues in their neutral state. The polyheterocyclic hybrids exhibited highly transmissive oxidized states, excellent optical contrasts both in the visible and in the near infrared, fast switching times and long-term redox switching stability as expected for practical ECP devices.

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