Stereoselective Total Synthesis of Rhoiptelol B via Prins Cyclization

Jhillu S. Yadav; Md. Ataur Rahman; N. Mallikarjuna Reddy; Attaluri R. Prasad; Ahmad Al Khazim Al Ghamdi; Ahmad Alkhazim Al Ghamdi

doi:10.1055/s-0033-1340181

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Stereoselective Total Synthesis of Rhoiptelol B via Prins Cyclization

Journal article

Peer reviewed

Stereoselective Total Synthesis of Rhoiptelol B via Prins Cyclization

Jhillu S. Yadav, Md. Ataur Rahman, N. Mallikarjuna Reddy, Attaluri R. Prasad, Ahmad Al Khazim Al Ghamdi and Ahmad Alkhazim Al Ghamdi

Synlett, Vol.25(5), pp.661-664

17/03/2014

DOI: https://doi.org/10.1055/s-0033-1340181

Abstract

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Abstract The stereoselective total synthesis of rhoiptelol B, a diarylheptanoid isolated from Rhoiptelea chiliantha is described. The tetrahydropyran ring was constructed by using Prins cyclization. The key steps involved in this synthesis are Prins cyclization, Mistunobu inversion, cross metathesis, Sharpless asymmetric dihydroxylation, and hydrogenolysis.

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Title: Stereoselective Total Synthesis of Rhoiptelol B via Prins Cyclization
Creators - without role: Jhillu S. Yadav - Indian Institute of Chemical Technology
Md. Ataur Rahman - Indian Institute of Chemical Technology
N. Mallikarjuna Reddy - Indian Institute of Chemical Technology
Attaluri R. Prasad - Indian Institute of Chemical Technology
Ahmad Al Khazim Al Ghamdi - King Saud University
Ahmad Alkhazim Al Ghamdi - King Saud University
Publication Details: Synlett, Vol.25(5), pp.661-664
Publisher: Georg Thieme Verlag
Identifiers: 9949976008331
Academic Unit: King Saud University
Language: English
Resource Type: Journal article