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Stereoselective total synthesis of the piperidine alkaloids, (+)-coniine, (+)-pseudoconhydrine, and (+)-sedamine through a common intermediate
Journal article   Peer reviewed

Stereoselective total synthesis of the piperidine alkaloids, (+)-coniine, (+)-pseudoconhydrine, and (+)-sedamine through a common intermediate

Gandham Satyalakshmi, Kanaparthy Suneel, Digambar Balaji Shinde and Biswanath Das
Tetrahedron: asymmetry, Vol.22(9), pp.1000-1005
15/05/2011
DOI: https://doi.org/10.1016/j.tetasy.2011.06.011

Abstract

Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical Physical Sciences Science & Technology
The stereoselective total synthesis of the piperidine alkaloids, (+)-coniine, (+)-pseudoconhydrine and (+)-sedamine has been achieved through a common intermediate generated from butane-1,4-diol. The synthetic sequence involves a Maruoka asymmetric allylation and ring-closing metathesis as the key steps. (C) 2011 Elsevier Ltd. All rights reserved.

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