Abstract
Three polymorphs of pyrene-2,7-bis(Bpin)(2) (1) and two of pyrene-2-(Bpin) (2), where Bpin = 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane, two different 1:1 co-crystals of 1 with toluene, and co-crystals of hexafluorobenzene (HFB) with 1 (of highly unusual 2:1 composition) and 2 (of usual 1:1 composition) were isolated, studied by X-ray diffraction and differential scanning calorimetry, and described using Hirshfeld surfaces and two-dimensional fingerprint plots. Centrosymmetric phases beta- and gamma-1 have densities respectively lower and higher than the chiral alpha-1; alpha- and beta-2 have different packing modes, both with Z' = 3. Compound 1 is prone to form channel host-guest structures, for example, alpha- and beta-1 center dot PhMe and 1 center dot 2HFB. The drastically different stabilities of alpha- and beta-1 center dot PhMe are discussed. The complex 2 center dot HFB has a mixed-stack packing motif. The structural versatility of 1 and 2 is explained by synthon frustration between structurally incongruent pyrene and Bpin moieties.