Abstract
We have recently synthesised a random poly(meta/para phenylene) (PMPP) by an electrochemical method from
p-methoxytoluene and fractionated on three-chain length compounds. Moreover, these fractions can be deposited by vacuum sublimation on indium tin oxide (ITO) substrates. Various characterisation methods are allowed which facilitated the understanding of the structural, electronic and optical properties of the PMPPs and a tentative of their correlation to chain length was presented.