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Structural and magnetic conformation of a cerocene [Ce(COT '')(2)](-) exhibiting a uniconfigurational f(1) ground state and slow-magnetic relaxation
Journal article   Peer reviewed

Structural and magnetic conformation of a cerocene [Ce(COT '')(2)](-) exhibiting a uniconfigurational f(1) ground state and slow-magnetic relaxation

Jennifer J. Le Roy, Ilia Korobkov, Jee Eon Kim, Eric J. Schelter and Muralee Murugesu
Dalton transactions : an international journal of inorganic chemistry, Vol.43(7), pp.2737-2740
01/01/2014
DOI: https://doi.org/10.1039/c3dt53280a
PMID: 24366363

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT'') led to the formation of a staggered COT'' arrangement in the cerocene-type sandwich complex with a well-defined oxidation state of +3 for the Ce ion.

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