Abstract
conventional solid state reaction method. Reitveld refinement of the x-ray diffraction patterns confirms the single phase character of all the compositions with orthorhombic structure having space group Pnma (No. 62). Dielectric properties of the samples at temperatures 200-475 K and frequencies 500 kHz-1 MHz authenticate the stabilization of ferroelectric phase with Mn substitution. Dielectric responses of these multiferroics have been analyzed carefully, in the light of "universal dielectric response" model. While cooling from room temperature to 20 K, systematic shifts in magnetization hysteresis loops indicate the presence of exchange bias (EB) phenomenon in the system. Magnetic behavior of these samples has been briefly discussed on the basis of "EB" model for granular systems. Temperature and magnetic field dependent magnetization data demonstrate enhanced magnetization due to the Mn substitution. Magnetocapacitance measurement reveals the magnetoelectric coupling for wide range of temperature (180-280 K) and decrease in dielectric loss at high magnetic field (3 T ). (C) 2010 American Institute of Physics. [doi: 10.1063/1.3386527]