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Sulphamic acid: An efficient, cost-effective and recyclable solid acid catalyst for three-component synthesis of homoallylic amines
Journal article   Peer reviewed

Sulphamic acid: An efficient, cost-effective and recyclable solid acid catalyst for three-component synthesis of homoallylic amines

J.S. Yadav, Hissana Ather, P. Purushothama Rao, R. Srinivasa Rao, K. Nagaiah and A.R. Prasad
Catalysis communications, Vol.7(10), pp.797-801
01/10/2006

Abstract

Allyl- n-tributylstannane Chemoselectivity Homoallylic alcohols Sulphamic acid (SA)
Homoallylic amines are synthesized by the three-component coupling reaction of aldehydes, anilines and allyltributylstannane using heterogeneous solid acid catalyst, sulphamic acid under solvent-free conditions in excellent yields. The catalyst can be recovered by simple filtration and can be recycled in subsequent reactions. The method is simple, cost-effective and environmentally benign.

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