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Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks
Journal article   Peer reviewed

Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks

Farid Nouar, Jarrod F. Eubank, Till Bousquet, Lukasz Wojtas, Michael J. Zaworotko and Mohamed Eddaoudi
Journal of the American Chemical Society, Vol.130(6), pp.1833-1835
13/02/2008
DOI: https://doi.org/10.1021/ja710123s
PMID: 18205363

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Here, we report a novel approach for the bottom-up assembly of hierarchical building blocks: simple molecular building blocks (MBBs) and the resultant supermolecular building blocks (SBBs) to build highly coordinated nets. A specific network, the (3,24)-connected rht, was used as a blueprint to construct a metal-organic framework where the MBBs/SBBs augment the net.

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