Abstract
Polypropylene (PP) is flammable material, which brings latent danger to the environment and human society. Therefore, developing new environmentally friendly and effective flame-retardant is one of the most important ways to improve the flame retardancy of PP and improve safety during its lifetime. Herein, we describe the synthesis of fivesym-2,4,6-trisubstituted-s-triazine derivatives, namely,N-2,N-4,N-6-triphenyl-1,3,5-triazine-2,4,6-triamine (TAT),N-2,N-4,N-6-tris(4-bromophenyl)-1,3,5-triazine-2,4,6-triamine (TBAT),N-2,N-4,N-6-tris(4-chlorophenyl)-1,3,5-triazine-2,4,6-triamine (TCAT), 4,4 ',4 ''-((1,3,5-triazine-2,4,6-triyl) tris(azanediyl)) triphenol (THAT), andN(2),N-4,N-6-tris(4-methoxyphenyl)-1,3,5-triazine-2,4,6-triamine (TMAT), from the reaction of cyanuric chloride andp-substituted aniline employing conventional heating or microwave irradiation. The prepared compounds characterized by different techniques, such as Fourier-transform infrared (FTIR), Ultra-Violet and Visible (UV-Vis), Nuclear Magnetic Resonance spectroscopy (H-1-NMR and(13)C-NMR), Thermogravimetric Analysis (TGA), and differential scanning calorimetry (DSC). The effect of substituent on the aniline moiety has great impact on its thermal stability, as observed from the TGA and DSC data. Based on the TGA and DSC results, three triazine derivatives TAT, TBAT, and TMAT were used as charring agents in the presence of different proportions of ammonium polyphosphate (APP) to form an intumescent flame-retardant (IFR) system, to improve the flame retardancy of PP. The flammability property of PP was investigated by a vertical burning test (UL94). The results of UL94 revealed that the TXAT/APP (IFR) system influence the PP and could improve the flame retardancy of PP. Best results were obtained with the mass ratio of APP and TXAT 2:1. When the IFR loading was 25 wt%, it displayed great influence and passed V-0 with TMAT, and V-1 with both TAT and TBAT in the UL94 test.