Abstract
In this work, we investigate the effects of titanium dioxide (TiO2) nanoparticle percentages on the optical and electrical properties of 3-(4-(dimethyl-amino)phenyl)-1-phenyl-(2E)-propen-1-one (DAAP). In order to achieve thin films, DAAP was dissolved in acetone and doped with different ratios of TiO2. The pure and composite mixtures were spin-coated onto a glass substrate. We investigated the influence of TiO2 on XRD patterns, absorption, energy band gaps, refractive indices, sheet resistance, resistivity, and Hall coefficients. We used the XRD technique to study the structure of DAAP pre-and post-doping with TiO2 nanoparticles. It was evident from the XRD patterns that the composite transformed from an amorphous to a polycrystalline nature and behaved similarly to titanium oxide crystals. The pure sample exhibited an absorption band of 409 nm. With the addition of TiO2, the whole absorption spectrum shifted to the blue region. For example, with a dopant percentage of 15%, the spectrum shifted to a wavelength of 368 nm. The energy band gap values increased with a dopant concentration from 2.65 eV of pure DAAP to 2.91 eV of maximum dopant percentage (15%). IP 203 8 109 10 On Thu 6 Feb 2023 14:33:23 The refractive index decreased to its lowesvaluof 2.47 with the increase in TiO2 concentration. The impact Copyright Ame rican Scientific Publishers of increasing TiO2 percentage highly improvedelctrical characteristics by reducing the sheet resistance and Delivered by Ingenta resistivity to 905 k(SI/sq) and 230 k on the (SI center dot cm), respectively. An optimized DAAP doped with 15% TiO2 has been used as an n-type layer on a p-type monocrystalline silicon wafer (Si (111)) to fabricate 71= 0.23% efficient solar cells. On the other hand, the amplified spontaneous emission (ASE) of the DAAP and dopant mixture was excited by the third harmonic generation (Aex = 355 nm). The pure DAAP exhibits an ASE peak at 535 nm. The intensity decreased rapidly with increased dopant concentration, whereas the full width at half-maximum (FWHM) increased slightly.