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Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers
Journal article   Peer reviewed

Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers

Mohammed Aljuaid, Evelina Liarou, James Town, James R. Baker, David M. Haddleton and Paul Wilson
Chemical communications (Cambridge, England), Vol.56(66), pp.9545-9548
19/08/2020
DOI: https://doi.org/10.1039/d0cc04067c
PMID: 32691028

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
[2+2]-Photodimerisation of monothiomaleimides has been demonstrated on functionalised linear and brush-like polymers. In water/acetonitrile (95 : 5) mixtures the rate of reaction is accelerated significantly by irradiation of the thiomaleimide end group (lambda(max)= 350 nm) with UV light, reaching full conversion within 10 minutes.

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