Synthesis and Comparative Studies of Cyclopalladated Complexes With Ortho C‒H Activation of Aromatic Rings Bearing Electron Donating and Electron Withdrawing Groups

A. M. Nassar; A. M. Hassan; N. M. Ibraheem; B. H. Hekal

doi:10.1080/15533174.2013.862641

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Synthesis and Comparative Studies of Cyclopalladated Complexes With Ortho C‒H Activation of Aromatic Rings Bearing Electron Donating and Electron Withdrawing Groups

A. M. Nassar, A. M. Hassan, N. M. Ibraheem and B. H. Hekal

Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry, Vol.45(6), pp.813-820

01/01/2015

DOI: https://doi.org/10.1080/15533174.2013.862641

Abstract

cyclopalladated complexes

electrophilic mechanism

spectroscopy

synthesis

The present study was undertaken to throw more light on the cyclopalladation mechanism. The reactivity of Schiff base ligands {N - (4methoxy benzylidene) 4-methoxyaniline (1) and N - (4nitro benzylidene) 4methoxyaniline (2)} by interaction with palladium (II) acetate is allowed to the isolation of different complexes (1a-f) and (2a-f). All the newly synthesized compounds are characterized using elemental analysis, IR, UV-VIS, 1 HNMR and mass spectral tools as well as TGA.

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Title: Synthesis and Comparative Studies of Cyclopalladated Complexes With Ortho C‒H Activation of Aromatic Rings Bearing Electron Donating and Electron Withdrawing Groups
Creators - without role: A. M. Nassar - Al Azhar University
A. M. Hassan - Chemistry Department, Faculty of Science, Al-Azhar University
N. M. Ibraheem - Organometallic Chemistry Department, National Research Center
B. H. Hekal - Chemistry Department, Faculty of Science, Al-Azhar University
Publication Details: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry, Vol.45(6), pp.813-820
Publisher: Taylor & Francis
Identifiers: 9913300208331
Academic Unit: Al Jouf University
Language: English
Resource Type: Journal article