Abstract
Polymer nanocomposites films, based on sodium alginate (NaAlg) and polyvi-nyl alcohol (PVA) complexed with zinc oxide nanoparticles (ZnO NPs) and iron oxide nanorods (Fe3O4 NRs) as nanofiller, were prepared by solution cast-ing technique. Different techniques were used to describe the prepared films. XRD and FTIR were used to pinpoint the complexation of the nanofiller with the polymer mixture. The XRD investigation verified the existence of the crys-talline peaks of ZnO/Fe3O4 NPs in the polymeric matrices. The average parti-cle size of nanocomposite was 23 nm. TEM image of the ZnO nanopowder confirming the spherical form of nanoparticles with average size 30 nm. The TEM image of Fe(3)O(4 )NRs reveals the free nanorods are around 9-23 nm in diameter and 130-350 nm in length. Peak positions and intensity variations in the FTIR absorption spectra are observed when the concentration increases from 2 to 8 wt% of ZnO NPs/Fe(3)O(4 )NRs. AC conductivity showed that the NaAlg/PVA-(8 wt%) ZnO/Fe3O4 NPs nanocomposites have higher electrical conductivity than NaAlg/PVA blend. For samples of 8% ZnO/Fe3O4, the sigma dcof nanocomposites reached 3.66 x 10(-8 )S cm( -1). ZnO/Fe3O4 nanoparticles consid-erably improved the nanocomposites' ability to conduct electricity. For the development of functional composite materials for the manufacture of electri-cal devices, sensors, and high-energy storage capacitors, the enhanced charac-teristics of synthesized NaAlg/PVA-ZnO/Fe3O4 nanocomposites can be helpful.