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Synthesis and crystal structure of a 3D copper(II)-silver(I) coordination polymer assembled through hydrogen bonding, pi-pi stacking and metal-pi interactions, {[Cu(phen)(2)(CN)][Ag(CN)(2)] center dot 3H(2)O}(n) (phen=1,10-phenanthroline)
Journal article   Open access  Peer reviewed

Synthesis and crystal structure of a 3D copper(II)-silver(I) coordination polymer assembled through hydrogen bonding, pi-pi stacking and metal-pi interactions, {[Cu(phen)(2)(CN)][Ag(CN)(2)] center dot 3H(2)O}(n) (phen=1,10-phenanthroline)

Sidra Nawaz, Tobias Rueffer, Heinrich Lang, Muhammad Ashraf Shaheen, Saeed Ahmad and Javed Hussain Shah
Zeitschrift für Naturforschung. B, A journal of chemical sciences, Vol.70(7), pp.455-459
01/07/2015
DOI: https://doi.org/10.1515/znb-2014-0264

Abstract

Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology
A copper(II) polymeric complex {[Cu(phen)(2)(CN)] [Ag(CN)(2)] center dot 3H(2)O}(n), 1 (phen = 1,10-phenanthroline), has been prepared and structurally characterized. The compound crystallizes in the monoclinic space group P2(1)/c with [Cu(phen)(2)(CN)](+) and [Ag(CN)(2)]-units and three water molecules. The cationic and anionic units are linked to each other through M-pi and pi-pi interactions. The array is extended further by hydrogen bonding and pi-pi interactions to form a 3D network.
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