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Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4'-bpy)3(H2O)2](PF6)22(4,4'- bpy)5H2O with nanosized channels clathrate large organic molecules
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Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4'-bpy)3(H2O)2](PF6)22(4,4'- bpy)5H2O with nanosized channels clathrate large organic molecules

Natalia Izarova, Maxim Sokolov, Alexander Rothenberger, Lukasz Ponikiewski, Dieter Fenske and Vladimir Fedin
Comptes rendus. Chimie, Vol.8(6-7), pp.1005-1010
01/06/2005
DOI: https://doi.org/10.1016/j.crci.2004.11.006

Abstract

A new metal-organic coordination polymer [Fe(4,4'-bpy)3(H2O)2](PF6)2*2(4,4'-bpy)*5H2O (1) (bpy = bipyridine) was prepared. X-ray structural analysis reveals that 1 is a three-dimensional network with nanosized channels constructed from one-dimensional coordination chains via non-covalent interactions between the pyridile rings. The channels clathrate large molecules of free 4,4'-bpy. Magnetic susceptibility measurement confirms the presence of isolated high-spin Fe(II) in 1.

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