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Synthesis and solid state self-assembly of an isatin–thiazoline hybrid driven by three self-complementary dimeric motifs
Journal article   Peer reviewed

Synthesis and solid state self-assembly of an isatin–thiazoline hybrid driven by three self-complementary dimeric motifs

Maqbool Ahmad, Humayun Pervez, Taibi Ben Hadda, Loic Toupet and Muhammad Moazzam Naseer
Tetrahedron letters, Vol.55(39), pp.5400-5403
24/09/2014
DOI: https://doi.org/10.1016/j.tetlet.2014.08.021

Abstract

Complementary motifs Isatin–thiazoline Layered structure Self-assembly Synthesis
An interesting isatin–thiazoline hybrid molecule having CNNN bonds has been synthesized and its solid state self-assembly behaviour was studied by X-ray diffraction technique. A layered structure based on hexameric supracycles, which are formed through three different self-complementary dimeric motifs, was obtained. The supramolecular forces involved in the stabilization of this structure are NH–O, CH–O, CH–N, CH–π, π–π, CH–Cl and unconventional N–O interactions.

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