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Synthesis and structure of [{(BuP)-P-t)(2)H}K center dot pmdeta](2), containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)(2)NMe]
Journal article   Peer reviewed

Synthesis and structure of [{(BuP)-P-t)(2)H}K center dot pmdeta](2), containing an organo diphosphido ligand [pmdeta = (Me2NCH2CH2)(2)NMe]

M A Beswick, A D Hopkins, L C Kerr, MEG Mosquera, J S Palmer, P R Raithby, A Rothenberger, D Stalke, A Steiner, AEH Wheatley, …
Chemical communications (Cambridge, England), (15), pp.1527-1528
07/08/1998
DOI: https://doi.org/10.1039/a803834a

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Reduction of [(BuP)-P-t](4\) with K metal (1:5 equiv,) followed by the addition of pmdeta and stoichiometric hydrolysis gives [(((BuP)-P-t)(2)H}K . pmdeta](2), a unique complex containing a [(BuP)-P-t(H)PBut](-) anion ligand homologous with a phosphido anion (R2P-).

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