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Synthesis, crystal structure, and luminescence properties of coordination polymers based on cadmium isonicotinates
Journal article   Peer reviewed

Synthesis, crystal structure, and luminescence properties of coordination polymers based on cadmium isonicotinates

M. S. Zavakhina, D. G. Samsonenko, M. P. Yutkin, D. N. Dybtsev and V. P. Fedin
Russian journal of coordination chemistry, Vol.39(4), pp.321-327
01/04/2013
DOI: https://doi.org/10.1134/S1070328413030081

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
Heating a solution of cadmium nitrate and isonicotinic acid in N,N'-dimethylformamide or dimethyl sulfoxide gave three new coordination polymers, [Cd(Inic)(2)] center dot 0.5DMF (I), [Cd-3(DMSO)(6)(Inic)(2)(SO4)(2)] (II), and [{Cd(DMSO)(Inic)}(2)(SO4)] center dot 2H(2)O (III), which were studied by X-ray crystallography. Compounds I and III were characterized by IR spectroscopy and elemental and thermogravimetric analyses and luminescence spectroscopy.

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