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Synthesis of 1,4-oxathian-2-ones by triton B-catalyzed one-pot reaction of epoxides with ethyl mercaptoacetate
Journal article   Peer reviewed

Synthesis of 1,4-oxathian-2-ones by triton B-catalyzed one-pot reaction of epoxides with ethyl mercaptoacetate

Lassaad Wechteti, Nejib Hussein Mekni and Moufida Romdhani-Younes
Heterocyclic communications, Vol.24(4), pp.187-191
01/08/2018

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
A rapid one-pot reaction of epoxides with ethyl mercaptoacetate furnishing 1,4-oxathian-2-ones in the presence of a catalytic amount of eco-friendly triton B is reported. High regioselectivity is due to the nucleophilic attack on the less sterically hindered carbon atom of the aliphatic unsymmetrical epoxide.

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