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Synthesis of 8-methyl[2.2]metacyclophanes and their charge-transfer complexes with tetracyanoethylene
Journal article   Peer reviewed

Synthesis of 8-methyl[2.2]metacyclophanes and their charge-transfer complexes with tetracyanoethylene

Tomoe Shimizu, Katsuhiro Hita, Shofiur Rahman and Takehiko Yamato
Journal of chemical research, Vol.2009(5), pp.293-297
01/05/2009
DOI: https://doi.org/10.3184/030823409X447718

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The regioselective 1:1 charge-transfer band of 13-substituted 8-methyl[2.2]metacyclophanes with tetracyanoethylene in CH2Cl2, attributable to the 8-methyl substituted benzene-site complex, are observed in the field of 556-605 nm, which is strongly affected by pi-electron density of the opposite aromatic ring.

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