Abstract
The quasi-solid-state electrolytes for flexible energy storage devices have indicated a great advancement during the last decade. However, further progress is still required to resolve non-flammability issues, high ionic conductivity, as well as electrochemical stability. Herein, we designed a new complex gel electrolyte with glycerol (Gly)/boric acid (BA) to address the non-flammability and maintained high conductivity by doping with potassium hydroxide (KOH). The Gly/3KOH/3BA combination was the optimum composition in terms of stability as well as hierarchical array for improved ionic conductivity to 2.9 × 10–3 S cm–1. Flexible electrochemical double-layer supercapacitors were assembled by using carbon composite electrodes, and the device provided a specific capacitance of 327 F g–1 at 1 A g–1. A remarkable cyclic stability of 93.4% capacitive performance is maintained after 10,000 cycles. The device indicated a specific energy of 45.4 W h kg–1 at a power of 920 W kg–1. Highly flexible devices constructed by using boron-incorporated gel electrolytes can provide a new strategy to assemble flexible devices for wearable electronics.