Abstract
Two sodalite phases (potassium sodalite (K.SD) and sodium sodalite (Na.SD)) were prepared using alkali fusion of kaolinite followed by a hydrothermal treatment step for 4 h at 90 degrees C. The synthetic phases were characterized as potential adsorbents for PO43- from the aqueous solutions and real water from the Rakos stream (0.52 mg/L) taking into consideration the impact of the structural alkali ions (K+ and Na+). The synthetic Na.SD phase exhibited enhanced surface area (232.4 m(2)/g) and ion-exchange capacity (126.4 meq/100 g) as compared to the K.SD phase. Moreover, the Na.SD phase exhibited higher PO43- sequestration capacity (Q(max) = 261.6 mg g(-1) and Q(sat) = 175.3 mg g(-1)) than K.SD phase (Q(max) = 201.9 mg g(-1) and Q(sat) = 127.4 mg g(-1)). The PO43- sequestration processes of both Na.SD and K.SD are spontaneous, homogenous, and exothermic reactions that follow the Langmuir isotherm and pseudo-first-order kinetics. Estimation of the occupied active site density validates the enrichment of the Na.SD phase with high quantities of active sites (Nm = 86.1 mg g(-1)) as compared to K.SD particles (Nm = 44.4 mg g(-1)). Moreover, the sequestration and Gaussian energies validate the cooperation of physisorption and weak chemisorption processes including zeolitic ion exchange reactions. Both Na.SD and K.SD exhibit significant selectivity for PO43- in the coexisting of other common anions (Cl-, SO42-, HCO3-, and NO3-) and strong stability properties. Their realistic application results in the complete adsorption of PO43- from Rakos stream water after 20 min (Na. SD) and 60 min (K.SD).