Abstract
Herein, this study successfully fabricates porous g-C3N4-based nanocomposites by decorating sheet-like nanostructured MnOx and subsequently coupling Au-modified nanocrystalline TiO2. It is clearly demonstrated that the as-prepared amount-optimized nanocomposite exhibits exceptional visible-light photocatalytic activities for CO2 conversion to CH4 and for H-2 evolution, respectively by approximate to 28-time (140 mu mol g(-1) h(-1)) and approximate to 31-time (313 mu mol g(-1) h(-1)) enhancement compared to the widely accepted outstanding g-C3N4 prepared with urea as the raw material, along with the calculated quantum efficiencies of approximate to 4.92% and 2.78% at 420 nm wavelength. It is confirmed mainly based on the steady-state surface photovoltage spectra, transient-state surface photovoltage responses, fluorescence spectra related to the produced center dot OH amount, and electrochemical reduction curves that the exceptional photoactivities are comprehensively attributed to the large surface area (85.5 m(2) g(-1)) due to the porous structure, to the greatly enhanced charge separation and to the introduced catalytic functions to the carrier-related redox reactions by decorating MnOx and coupling Au center dot TiO2, respectively, to modulate holes and electrons. Moreover, it is suggested mainly based on the photocatalytic experiments of CO2 reduction with isotope (CO2)-C-13 and D2O that the produced center dot CO2 and center dot H as active radicals would be dominant to initiate the conversion of CO2 to CH4.