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Synthesis of New Spirocyclopropane and Oxadiazole Products
Journal article   Peer reviewed

Synthesis of New Spirocyclopropane and Oxadiazole Products

Amel Haouas, Naoufel Ben Hamadi and Moncef Msaddek
Journal of heterocyclic chemistry, Vol.52(6), pp.1765-1768
11/2015

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
In explorations of synthesis and chemistry of spiroheterocycles, we found that the reaction of 2-diazopropane with arylidene-benzofuran-2(3H)-one and arylidene-benzofuran-3(2H)-one derivatives generated the spirocyclopropane products. In addition to the expected cycloadducts, an unexpected oxadiazole was formed in some cases. The structures of the obtained adducts have been assigned by means of spectroscopic methods.

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