Abstract
Five new thiophenes, namely, N-[(3-bromo-2-methylthiophen-5-yl) methylene]-4-methoxyaniline (4a), N-[(3-bromo-2-methylthiophen- 5-yl) methylene]-3,4-dimethoxyaniline (4b), N-[(3-bromo-2-methylthiophen-5-yl) methylene]-3,4-dimethylaniline (4c), 3-[(3-bromo-2-methylthiophen-5-yl) methyleneamino]-2-methylquinazolin-4(3H)-one (4d), and 3-[(3-bromo-2-methylthiophen- 5-yl) methyleneamino]-2-isopropylquinazolin-4(3H)-one (4e), have been synthesized. All of these materials brought about a reduction in the level of photodegradation of poly(vinyl chloride) (PVC) films containing the synthesized thiophenes (0.5%; by weight). The results obtained showed that the extent of photostabilization of PVC in the presence of an additive was in the order 4e > 4d > 4b > 4a > 4c. For the most favorable additive (4e), the rate of appearance of infrared absorption bands of degradation products was reduced by around two-thirds, while the quantum yield of chain scission was calculated to be reduced by a factor of more than one thousand. It is suggested that the additives may help stabilize PVC by direct absorption of UV radiation and dissipation of the energy as heat or that electrostatic attraction between the additives and PVC may assist transfer of energy from excited state PVC to the additive, from where it can be dissipated.