Abstract
Core-shell micromembrane reactors are a novel class of materials where a catalyst and a shape-selective membrane are synergistically housed in a single particle In this work, we report the synthesis of micrometer-sized core shell particles containing a catalyst core and a thin permselective zeolite shell and their application as a micromembrane reactor for the selective hydrogenation of the 1-hexene and 3,3-dimethyl-1-butene isomers The bare catalyst, which is made from porous silica loaded with catalytically active nickel, showed no reactant selectivity between hexene isomers, but the core shell particles showed high selectivities up to 300 for a 1-hexene conversion of 90%