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Synthesis of electron-poor hexa-peri-hexabenzocoronenes
Journal article   Peer reviewed

Synthesis of electron-poor hexa-peri-hexabenzocoronenes

David J. Jones, Balaji Purushothaman, Shaomin Ji, Andrew B. Holmes and Wallace W. H. Wong
Chemical communications (Cambridge, England), Vol.48(65), pp.8066-8068
21/08/2012
DOI: https://doi.org/10.1039/c2cc33892k
PMID: 22767202

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The oxidative cyclodehydrogenation of electron-poor arenes was achieved using DDQ-CF3SO3H resulting in hexa-peri-hexabenzocoronenes with electron withdrawing Br, F and CF3 groups. This method will lead to their expansion into a new class of electron transport materials.

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