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Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)
Journal article   Peer reviewed

Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)

Travis Lundrigan, Carla L. M. Jackson, Md Imam Uddin, Lloyd A. Tucker, Adeeb Al-Sheikh Ali, Anthony Linden, T. Stanley Cameron and Alison Thompson
Canadian journal of chemistry, Vol.90(8), pp.693-700
01/08/2012
DOI: https://doi.org/10.1139/V2012-045

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The synthesis and characterization of the first heteroleptic pyrrolide/2,2'-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)(2)Cl-2.2H(2)O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.

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