Synthesis of nanocrystalline tetragonal zirconia by inorganic metathesis reaction

Fengxi Chen; Lin Huang; Ziyi Zhong; Geok Joo Gan; Sin Man Kwan; Fethi Kooli; F. Kooli

doi:10.1016/j.matchemphys.2005.08.019

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Synthesis of nanocrystalline tetragonal zirconia by inorganic metathesis reaction

Journal article

Peer reviewed

Synthesis of nanocrystalline tetragonal zirconia by inorganic metathesis reaction

Fengxi Chen, Lin Huang, Ziyi Zhong, Geok Joo Gan, Sin Man Kwan, Fethi Kooli and F. Kooli

Materials chemistry and physics, Vol.97(1), pp.162-166

10/05/2006

DOI: https://doi.org/10.1016/j.matchemphys.2005.08.019

Abstract

Metathesis

Modified sol–gel reaction

Organic melts

Tetragonal zirconia

Nanocrystalline t-ZrO 2 particles (plate-like morphology with crystallite size of ca. 13 nm) have been prepared by a metathesis reaction between ZrO(NO 3) 2 and NaOH at 150 °C. A reaction scheme comprising hydroxylation and condensation of the zirconium center was proposed to explain the observation. Fine and uniform t-ZrO 2 particulates with smaller crystallite size (ca. 11 nm) can be produced by carrying out the same reaction in molten 1,12-diaminododecane.

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Title: Synthesis of nanocrystalline tetragonal zirconia by inorganic metathesis reaction
Creators - without role: Fengxi Chen - Institute of Chemical and Engineering Sciences
Lin Huang - Institute of Chemical and Engineering Sciences
Ziyi Zhong - Institute of Chemical and Engineering Sciences
Geok Joo Gan
Sin Man Kwan - Institute of Chemical and Engineering Sciences
Fethi Kooli - Institute of Chemical and Engineering Sciences
F. Kooli - Taibah University
Publication Details: Materials chemistry and physics, Vol.97(1), pp.162-166
Publisher: Elsevier B.V
Identifiers: 9930222408331
Academic Unit: Taibah University
Language: English
Resource Type: Journal article