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Synthesis of some new 3-(bromophenyl)isocoumarins and their conversion to (dl)-3,4-dihydroisocoumarins
Journal article   Peer reviewed

Synthesis of some new 3-(bromophenyl)isocoumarins and their conversion to (dl)-3,4-dihydroisocoumarins

M T Hussain, N H Rama and A Malik
Indian journal of chemistry. Sect. B. Organic chemistry, including medicinal chemistry, Vol.40(5), pp.372-376
01/05/2001

Abstract

Chemistry Chemistry, Organic Physical Sciences Science & Technology
3-(Bromophenyl)isocoumarins 8a-c have been synthesized by the condensation of homophthalic acid 6 with bromobenzoyl chlorides 7a-c which on alkaline hydrolysis give keto-acids 9a-c. (dl)-3-(Bromophenyl)-3,4-dihydroisocoumarins 12a-c are obtained by reduction of keto-acids 9a-c to racemic hydroxy-acids 11a-c followed by cyclodehydration using acetic anhydride. All the compounds have been examined in vitro for their antimicrobial activity.

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