Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

Maxim P. Yutkin; Marina S. Zavakhina; Alexander V. Virovets; Danil N. Dybtsev; Vladimir P. Fedin; Tetsuro Kusamoto; Hiroshi Nishihara

doi:10.1016/j.ica.2010.10.015

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Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

Journal article

Peer reviewed

Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

Maxim P. Yutkin, Marina S. Zavakhina, Alexander V. Virovets, Danil N. Dybtsev, Vladimir P. Fedin, Tetsuro Kusamoto and Hiroshi Nishihara

INORGANICA CHIMICA ACTA, Vol.365(1), pp.513-516

15/01/2011

DOI: https://doi.org/10.1016/j.ica.2010.10.015

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

New metal-organic coordination polymer, (Me3NH)[Fe-3(mu(3)-O)(mu-HCOO)(8)]center dot DMF (1), was synthesized by heating of Fe(NO3)(3)center dot 9H(2)O and [NH(CH3)(3)]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe3O(mu-HCOO)(6) cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between Fe-III ions in the cluster and intercluster magnetic interaction. (C) 2010 Elsevier B.V. All rights reserved.

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Title: Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core
Creators - without role: Maxim P. Yutkin - Nikolaev Institute of Inorganic Chemistry
Marina S. Zavakhina - Nikolaev Institute of Inorganic Chemistry
Alexander V. Virovets - Nikolaev Institute of Inorganic Chemistry
Danil N. Dybtsev - Nikolaev Institute of Inorganic Chemistry
Vladimir P. Fedin - Nikolaev Institute of Inorganic Chemistry
Tetsuro Kusamoto - The University of Tokyo
Hiroshi Nishihara - The University of Tokyo
Publication Details: INORGANICA CHIMICA ACTA, Vol.365(1), pp.513-516
Publisher: Elsevier
Number of pages: 4
Grant note: 107 / Siberian Branch of the Russian Academy of Sciences; Russian Academy of Sciences 5.6.1 / Russian Academy of Sciences 21108002; 21108001 / Grants-in-Aid for Scientific Research; Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT); Japan Society for the Promotion of Science; Grants-in-Aid for Scientific Research (KAKENHI) 09-03-90414; 09-03-12112 / Russian Foundation for Basic Research; Russian Foundation for Basic Research (RFBR); Spanish Government
Identifiers: 9946096708331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article